Title Prof. First Name MARILYN Last Name MILTON
Designation Professor
Department Department of Chemistry
Email
Webpage
Phone.no 27666646
Employement Info
Employee Type Nature Of Employment
Teaching Permanent
Educational Qualifications
Degree/Certification Name Institution Year of Completion
Certificate Japan Foundation and Japan Educational Exchanges and Services 2012
Ph.D. - Ph.D. Indian Institute of Technology, Delhi 2002
PG Indian Institute of Technology, Delhi 1997
UG University of Delhi 1995
Teaching Experience (Within Institution)
Designation Duration
Professor 26-10-2013 To 20-07-2022 (8 years, 8 months, 24 days)
Associate Professor 15-11-2008 To 25-10-2013 (4 years, 11 months, 10 days)
Reader 10-12-2007 To 14-11-2008 (11 months, 4 days)
Assistant Professor (Reader's grade) 14-11-2005 To 07-12-2007 (2 years, 23 days)
Administrative Experience (Within Institution)
Designation Duration
Provost 01-04-2021 To 31-03-2022 (11 months, 30 days)
Research Supervision Overview
PhD Scholars Supervised PhD Degrees Awarded Theses Submitted
0 12 0
Research Publications
Title of Article Type of Publication Name of Journal ISSN Journal Volume Year Link to Article DOI (Digital Object Identifier)
N, N’-Disubstituted benzimidazolium salts: Synthesis, characterization, micromolar detection of Fe(III) ions in aqueous system, biological evaluation and molecular docking studies Research Papers in Peer Reviewed Journals ChemistrySelect 7 doi.org/10.1002/slct.202203239

Multi stimuli responsive non-doped red emitting AIEE active phenothiazine based chalcones: Crystal structure, solvatochromism, turn-on mechanofluorochromism and acidochromism Research Papers in Peer Reviewed Journals European Journal of Organic Chemistry doi.org/10.1002/ejoc.202201024

Design and synthesis of multi-stimuli responsive π-extended phenothiazine aldehydes: Solvatochromism, acidochromism, moisture detection and fluorochromic sensing of amine vapors Research Papers in Peer Reviewed Journals Dyes and Pigments 205 10.1016/j.dyepig.2022.110474

AIEE-TICT quadrupolar push-pull quinoxaline derivatives displaying solvatochromism, acidofluorochromism and logic gate operation Research Papers in Peer Reviewed Journals Journal of Molecular Structure 1264 10.1016/j.molstruc.2022.133275

Synthesis of acceptor-donor-acceptor based phenothiazine-5-oxide aldehydes displaying large Stokes shift- “on-off-on” acidofluorochromic switch and molecular logic gate operation Research Papers in Peer Reviewed Journals Journal of Photochemistry and Photobiology A: Chemistry 430 10.1016/j.jphotochem.2022.113944

Novel Y-shaped AIEE-TICT active π-extended quinoxalines-based donor–acceptor molecules displaying acidofluorochromism and temperature dependent emission Research Papers in Peer Reviewed Journals Journal of Photochemistry and Photobiology A: Chemistry 424 10.1016/j.jphotochem.2021.113630

Y-shaped novel AIEE active push-pull quinoxaline derivatives displaying acidochromism and use towards white light emission by controlled protonation Research Papers in Peer Reviewed Journals Dyes and Pigments 195 10.1016/j.dyepig.2021.109690

Y-shaped AIEE active quinoxaline-benzothiazole conjugate for fluorimetric sensing of nitroaromatics in aqueous media Research Papers in Peer Reviewed Journals Journal of Photochemistry and Photobiology A: Chemistry 419 10.1016/j.jphotochem.2021.113444

Novel push-pull based phenothiazine-benzothiazole derivatives integrated with molecular logic gate operation for reversible volatile acid detection Research Papers in Peer Reviewed Journals Journal of Molecular Structure 1243 10.1016/j.molstruc.2021.130768

Fluorescent dyes for moisture detection in organic solvents: Push-pull based phenothiazine aldehydes with large Stokes shifts Research Papers in Peer Reviewed Journals Journal of Photochemistry and Photobiology A: Chemistry 402 10.1016/j.jphotochem.2020.112804

Smart organic materials with acidochromic properties Research Papers in Peer Reviewed Journals Current Organic Chemistry 24 10.2174/1385272824999200729132853

AIEE active novel red-emitting D-π-A phenothiazine chalcones displaying large Stokes shift, solvatochromism and “turn-on” reversible mechanofluorochromism Research Papers in Peer Reviewed Journals Dyes and Pigments 181 10.1016/j.dyepig.2020.108539

Novel thiazoline-phenothiazine based “push-pull” molecules as fluorescent probes for volatile acids detection Research Papers in Peer Reviewed Journals Journal of Photochemistry and Photobiology A: Chemistry 397 10.1016/j.jphotochem.2020.112509

Computational prediction of interaction and pharmacokinetics profile study for polyamino-polycarboxylic ligands on binding with human serum albumin Research Papers in Peer Reviewed Journals New Journal of Chemistry 44 10.1039/c9nj05594k

Design, Synthesis and Characterisation of Novel Phenothiazine-Based Triazolopyridine Derivatives: Evaluation of Anti-Breast Cancer Activity on Human Breast Carcinoma Research Papers in Peer Reviewed Journals ChemistrySelect 4 10.1002/slct.201903203

Design and synthesis of novel V-shaped AIEE active quinoxalines for acidochromic applications Research Papers in Peer Reviewed Journals Dyes and Pigments 165 10.1016/j.dyepig.2019.02.038

Logic gate based novel phenothiazine-pyridylhydrazones: Halochromism in solid and solution state Research Papers in Peer Reviewed Journals Dyes and Pigments 164 10.1016/j.dyepig.2019.01.038

Novel 2-arylbenzothiazoles: selective chromogenic and fluorescent probes for the detection of picric acid Research Papers in Peer Reviewed Journals ChemistrySelect 3 10.1002/slct.201800645

Novel Phenothiazine-5-oxide Based Push-Pull Molecules: Synthesis and Fine-Tuning of Electronic, Optical and Thermal Properties Research Papers in Peer Reviewed Journals ChemistrySelect 3 10.1002/slct.201800131

Dicationic imidazolium salts as fluorescent probes for selective detection of Fe3+ ion in pure aqueous media Research Papers in Peer Reviewed Journals Journal of Photochemistry and Photobiology A: Chemistry 356 10.1016/j.jphotochem.2018.02.003

Synthesis of novel AIEE active pyridopyrazines and their applications as chromogenic and fluorogenic probes for Hg 2+ detection in aqueous media Research Papers in Peer Reviewed Journals New Journal of Chemistry 42 10.1039/c7nj04573e

Multi-Stimuli Response Displaying Novel Phenothiazine-Based Non-Planar D-π-A Hydrazones: Synthesis, Characterization, Photophysical and Thermal studies Research Papers in Peer Reviewed Journals ChemistrySelect 2 doi.org/10.1002/slct.201702684

Small Nonplanar Phenothiazine-5-oxide-Based Molecules: Structural Characterization, Photophysical, Thermal and Computational Studies Research Papers in Peer Reviewed Journals ChemistrySelect 2 10.1002/slct.201700279

A Base-and Metal-free Protocol for the Synthesis of 2-Aryl/heteroaryl Thiazolines Research Papers in Peer Reviewed Journals ChemistrySelect 2 10.1002/slct.201601553

Selective and sensitive novel benzimidazolium-based fluorescent probes for micromolar detection of Fe3+ ions in pure aqueous media Research Papers in Peer Reviewed Journals Journal of Photochemistry and Photobiology A: Chemistry 335 10.1016/j.jphotochem.2016.11.010

Flexible, dicationic imidazolium salts for in situ application in palladium-catalysed Mizoroki--Heck coupling of acrylates under aerobic conditions Research Papers in Peer Reviewed Journals Applied Organometallic Chemistry 30 10.1002/aoc.3503

Design, synthesis and relaxation studies of triazole linked gadolinium (III)--DO3A-BT-bistriazaspirodecanone as a potential MRI contrast agent Research Papers in Peer Reviewed Journals New Journal of Chemistry 40 10.1039/c5nj03220b

Tunable phenothiazine hydrazones as colour displaying, ratiometric and reversible pH sensors Research Papers in Peer Reviewed Journals Tetrahedron Letters 56 10.1016/j.tetlet.2015.10.041

Design, synthesis and preliminary evaluation of a novel SPECT DTPA-bis-triazaspirodecanone conjugate for D 2 receptor imaging Research Papers in Peer Reviewed Journals RSC Advances 4 10.1039/c4ra07004f

Synthesis of 2-aryl/heteroaryloxazolines from nitriles under metal-and catalyst-free conditions and evaluation of their antioxidant activities Research Papers in Peer Reviewed Journals The Journal of organic chemistry 79 dx.doi.org/10.1021/jo501430p

Oxime-dipeptides as anticholinesterase, reactivator of phosphonylated-serine of AChE catalytic triad: probing the mechanistic insight by MM-GBSA, dynamics simulations and DFT analysis Research Papers in Peer Reviewed Journals Journal of Biomolecular Structure and Dynamics 33 10.1080/07391102.2014.921793

Designed benzimidazolium salts: Modulation of fluorescence response towards metal cations in pure aqueous media Research Papers in Peer Reviewed Journals Sensors and Actuators B: Chemical 202 10.1016/j.snb.2014.05.037

In silico thermodynamics stability change analysis involved in BH4 responsive mutations in phenylalanine hydroxylase: QM/MM and MD simulations analysis Research Papers in Peer Reviewed Journals Journal of Biomolecular Structure and Dynamics 33 10.1080/07391102.2014.897258

Synthesis of new benzimidazolium salts with tunable emission intensities and their application as fluorescent probes for Fe3+ in pure aqueous media Research Papers in Peer Reviewed Journals Tetrahedron Letters 55 10.1016/j.tetlet.2014.01.127

Sodium carbonate mediated regioselective synthesis of novel N-(hydroxyalkyl) cinnamamides Research Papers in Peer Reviewed Journals Tetrahedron Letters 54 10.1016/j.tetlet.2013.10.086

Perception into hypoxia selectivity and electronic features of symmetrically substituted bisthiosemicarbazone ligands and their copper complexes: DFT and QM/MM docking Research Papers in Peer Reviewed Journals MedChemComm 4 10.1039/c2md20333b

Synthesis of [DTPA-bis(D-ser)] Chelate (DBDSC): An Approach for the Design of SPECT Radiopharmaceuticals Based on Technetium Research Papers in Peer Reviewed Journals Current Radiopharmaceuticals, 2012, 5, 348-355 5 10.2174/1874471011205040348

Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols Research Papers in Peer Reviewed Journals European Journal of Organic Chemistry 10.1002/ejoc.200500858

Design, synthesis, and structural aspects of chalcogen-substituted pyridine dicarboxamide donors and their reactions Research Papers in Peer Reviewed Journals Tetrahedron letters 47 10.1016/j.tetlet.2005.12.004

Ruthenium-catalyzed formation of aryl (diphenyl) phosphine oxides by reactions of propargylic alcohols with diphenylphosphine oxide Research Papers in Peer Reviewed Journals Organic Letters 7 10.1021/ol0515311

Ruthenium-Catalyzed Propargylic Substitution Reactions of Propargylic Alcohols with Oxygen-, Nitrogen-, and Phosphorus-Centered Nucleophiles Research Papers in Peer Reviewed Journals Chemistry--A European Journal 11 10.1002/chem.200400833

A facile access to chalcogen and dichalcogen bearing dialkylamines and diols Research Papers in Peer Reviewed Journals Tetrahedron letters 46 10.1016/j.tetlet.2004.12.035

Design and synthesis of organochalcogen (Se or Te) based multifunctional derivatives: structural determination and dynamic behavior of 2-chloro-4, 6-bis (phenylselenoethylamino)-1, 3, 5-triazines Research Papers in Peer Reviewed Journals Tetrahedron letters 45 10.1016/j.tetlet.2004.09.132

Ruthenium-and gold-catalysed sequential reactions: a straightforward synthesis of substituted oxazoles from propargylic alcohols and amides Research Papers in Peer Reviewed Journals Chemical communications 10.1039/b411180j

Double phosphinylation of propargylic alcohols: a novel synthetic route to 1, 2-bis (diphenylphosphino) ethane derivatives Research Papers in Peer Reviewed Journals Organic Letters 6 10.1021/ol048347k

Synthesis of beta-ketoenamine donors having O, N, Se/Te donor functionalities and their reaction chemistry with Pd (II) and Pt (II) metal ions Research Papers in Peer Reviewed Journals Tetrahedron Letters 45 10.1016/j.tetlet.2004.07.057

An efficient synthesis and structural aspects of hexakis (arylseleno) benzenes and hexakis (arylselenomethyl) benzenes Research Papers in Peer Reviewed Journals Tetrahedron letters 45 10.1016/j.tetlet.2004.07.020

An efficient and facile one-pot synthesis of structurally unique 2, 4, 6-tris (arylchalcogeno)-1, 3, 5-triazine and 1, 3, 5-tris (arylchalcogeno)-2, 4, 6-trimethylbenzene Research Papers in Peer Reviewed Journals Tetrahedron letters 45 10.1016/j.tetlet.2004.06.128

Novel Ruthenium-and Platinum-Catalyzed Sequential Reactions: Synthesis of Tri-and Tetrasubstituted Furans and Pyrroles from Propargylic Alcohols and Ketones Research Papers in Peer Reviewed Journals Angewandte Chemie International Edition 42 10.1002/anie.200351170

Design, synthesis and structural aspects of NH2 (CH2) nE (CH2) nNH2 (n= 2 or 3; E= Se or Te) N2Se or N2Te donors and its complexes with Group 12 metals Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 172 10.1080/10426500108046656

Design and synthesis of heteroatom bearing organoselenium donor and its reactivity towards platinum (II) metal Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 169:1 10.1080/10426500108546613

Design, synthesis and structural aspects of terdentate (N, O, Se/Te) donors and their competitive coordination behavior towards Pt (II) Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 172 10.1080/10426500108046655

Design, synthesis and structural aspects of acyclic N3E2 (E= Se or Te) type donors and its complexes with Group 12 metals Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 172 10.1080/10426500108046654

New acyclic chalcogen bearing ligands and their complexation reactions Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 136 10.1080/10426509808545955

Non-Journal Publications
Title of Publication Type of Publication Publisher Role ISBN Year Link to Publication Level
Synthesis of D-serine based SPECT radiopharmaceutical for tumor imaging: 99m Tc-DTTA-bis (D-serine) Full Paper in Conference Proceedings/Other Society of Nuclear Medicine Co-Author National
Design and Synthesis of novel PET ligand ([N-methyl-11C]-bistriazaspirodecanone) for imaging of Dopamine receptor. Full Paper in Conference Proceedings/Other SPRINGER 233 SPRING ST, NEW YORK, NY 10013 USA
Design and Synthesis of high specific activity Ga-68 (III)-DOTA-Aib-Ranatensin Analogue to target GRP-R positive tumors Full Paper in Conference Proceedings/Other SPRINGER 233 SPRING ST, NEW YORK, NY 10013 USA
Synthesis and biological evaluation of F-18 labeled 8-(3-(4-(3-fluoropropyl)-1H-1, 2, 3-triazol-1-yl) propyl)-1-phenyl-1, 3, 8-triazaspiro [4.5] decan-4-one for PET imaging of D2 receptor. Full Paper in Conference Proceedings/Other SPRINGER 233 SPRING ST, NEW YORK, NY 10013 USA
Synthesis and biological evaluation of Bis-2-(1, 3, 8-triazaspiro [4, 5] decan-4-one) ethylamine based radiopharmaceuticals for neuroendocrine tumor Full Paper in Conference Proceedings/Other SPRINGER 233 SPRING ST, NEW YORK, NY 10013 USA
DOTA-G (KDP) 2 PET neuroimaging biomarker: Design, synthesis and biological evaluation Full Paper in Conference Proceedings/Other SPRINGER 233 SPRING ST, NEW YORK, NY 10013 USA
Design and synthesis of phenothiazine based D-pi-A chromophores exhibiting mechanofluorochromism and aggregation-induced emission Full Paper in Conference Proceedings/Other AMER CHEMICAL SOC 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Research Projects
Project Title Project Type Year Of Sanction Outcome/Output Duration
Quinoxaline and pyridopyrazine-based donor-acceptor molecules and their applications Minor 2022 Research papers 31-08-2022 To 15-02-2023 (5 months, 15 days)
Development of phenothiazine-based push-pull systems for new functional molecules and materials Minor 2021 29-10-2021 To 15-03-2022 (4 months, 14 days)
Synthesis of phenothiazine-based push-pull molecules with aggregation induced emission enhancement (AIEE) properties and its applications Minor 2020 31-12-2020 To 15-03-2021 (2 months, 12 days)
Synthesis of novel π-extended phenothiazine derivatives and their applications Minor 2023 Research papers 31-08-2023 To 15-02-2024 (5 months, 15 days)
Synthesis and characterization of novel phenothiazine-based red-light emitting dyes and their applications Minor 2024 Ongoing since 06-09-2024 (1 months, 24 days)
Honors and Awards
Name of the Award Awarding Body Award Category Level Award Date
Selected to attend Global Chemists’ Code of Ethics Science and Technology Leadership Program , Melbourne, Australia American Chemical Society Research International 11-05-2017
Monbukhagakusho (MEXT) Scholarship Japanese Government Research International 01-10-2002
Associate to the Committee on Chemical Safety American Chemical Society Academic International 01-01-2024
Patents
Patent Title Patent Number Patent Level Patent Status
Novel brominated phenothiazine scaffolds and methods thereof 301082 National
Talk Poster Presented
Name of the Activity Role Date of Activity
Multi-stimuli responsive fluorochromic switching in phenothiazine derivatives, delivered by Prof. M. D. Milton in the Young Scientist Conclave (online) held on July 30-31, 2022 Organized by The Indian Chemical Society Invited Talk 30-07-2022
“Smart organic materials” Prof. M. D. Milton delivered a talk in online Refresher Course on Chemistry for University and College teachers organized by CPDHE on 31st October 2020 Invited Talk 31-10-2020
Shalu Gupta, M. D. Milton, “Novel AIEE active pyridopyrazine and quinoxaline derivatives for mercury ion sensing and acidochromic applications” Oral Presentation by Dr. Shalu Guptain the First Virtual JNOST Symposium XVI-J-NOST Oral Presentation 01-11-2020
M. Lamoria, M. D. Milton, “Novel AIEE active quinoxaline and pyridopyrazine derivatives as multi-stimuli responsive materials” Oral lecture by Ms. M. Lamoria. Awarded best oral ACS Materials Award Speaker 17-12-2022
“Y-shaped quinoxalines-based AIEgens: design, synthesis and applications” Invited Short Lecture presented by M.D.Milton Speaker 16-12-2022
Invited Lecture on Phenothiazine derivatives as smart organic materials presented by M.D.Milton Speaker 28-03-2023
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