Title Prof. First Name Sandeep Last Name Kaur
Designation Professor
Department Department of Chemistry
Email skaur@chemistry.du.ac.in
Webpage
Phone.no 01127667794
Employement Info
Employee Type Nature Of Employment
Teaching Permanent
Educational
Degree/Certification Institution Year
Ph.D. - Mixed valency and valence state distributions in polynuclear ruthenium frameworks IIT Bombay 2007
PG Burdwan University 2002
UG Hooghly Mohsin College, Burdwan University 2000
HSC West Bengal Council of Higher Secondary Education (WBCHSE) 1997
SSC Indian Certificate of Secondary Education (ICSE) 1995
Qualifications
Examination Name Conducted By Date of Passing
NET 2002-07-01
Fellowship
Fellowship Name Fellowship Body Level
Wenner-Gren Fellowship Wenner-Gren Foundation, Sweden International
Administrative experience within Institution
Designation Institution Name Duration from Duration to
Resident Tutor Rajiv Gandhi Hostel for Girls, University of Delhi 2011-05-16 2018-01-31
Research Guidance
PhD scholars under Supervision Awarded PhD Submitted
4 7 1
Research Publications
Article Name Publication Type Journal Name ISSN No Volume Year URL DOI
2-Mercaptobenzimidazole ligand-based models of the [FeFe] hydrogenase: synthesis, characterization and electrochemical studies Research Papers in Peer Reviewed Journals Journal of Chemical Sciences 0973-7103 (web) 134 2022 https://doi.org/10.1007/s12039-022-02027-3
Mechanism of Diiron Hydrogenase Complexes Controlled by Nature of Bridging Dithiolate Ligand Research Papers in Peer Reviewed Journals ChemistryOpen 2191-1363 11 2022 https://doi.org/10.1002/open.202100238
Barriers to Full Participation in the Open Science Life Cycle among Early Career Researchers Research Papers in Peer Reviewed Journals Data Science Journal 1683-1470 21 2022 http://doi.org/10.5334/dsj-2022-002
Mitigating losses: how scientific organisations can help address the impact of the COVID-19 pandemic on early-career researchers Research Papers in Peer Reviewed Journals Humanities and Social Sciences Communications 2662-9992 8 2021 https://doi.org/10.1057/s41599-021-00944-1
A Homobivalent SPECT Radioligand‐Serinol Appended Methoxyphenyl Piperazine Derivative for Serotonin Receptor Imaging Research Papers in Peer Reviewed Journals ChemistrySelect 2365-6549 (web) 6 2021 https://doi.org/10.1002/slct.202100549
Switching Site Reactivity in Hydrogenase Model Systems by Introducing a Pendant Amine Ligand Research Papers in Peer Reviewed Journals ACS Omega 2470-1343 (web) 6 2021 https://doi.org/10.1021/acsomega.0c04901
Mononuclear Mn complexes featuring N, S-/N, N-donor and 1, 3, 5-triaza-7-phosphaadamantane ligands: synthesis and electrocatalytic properties Research Papers in Peer Reviewed Journals New Journal of Chemistry 1369-9261 (web) 45 2021 https://doi.org/10.1039/D1NJ02104D
Macrocyclic butterfly iron cluster complexes: electrochemical investigations Research Papers in Peer Reviewed Journals Journal of Chemical Sciences 0973-7103 (web) 132 2020 https://doi.org/10.1007/s12039-020-01830-0
Electrochemical aspects of restricted rhenium (I)-based supramolecular complexes with semi-rigid benzimidazolyl and rigid hydroxyquinone ligands Research Papers in Peer Reviewed Journals Journal of Chemical Sciences 0973-7103 (web) 132 2020 https://doi.org/10.1007/s12039-019-1689-3
Mono-and dinuclear mimics of the [FeFe] hydrogenase enzyme featuring bis (monothiolato) and 1, 3, 5-triaza-7-phosphaadamantane ligands Research Papers in Peer Reviewed Journals Inorganica Chimica Acta 0020-1693 504 2020 https://doi.org/10.1016/j.ica.2020.119442
Structural and HER studies of diphosphine-monothiolate complexes [Fe2 (CO) 4 (μ-naphthalene-2-thiolate) 2 (μ-dppe)] and [Fe2 (CO) 4 (μ-naphthalene-2-thiolate) 2 (μ-DPEPhos)] Research Papers in Peer Reviewed Journals Inorganica Chimica Acta 0020-1693 501 2020 https://doi.org/10.1016/j.ica.2019.119227
Manganese complexes: hydrogen generation and oxidation Research Papers in Peer Reviewed Journals European Journal of Inorganic Chemistry 1099-0682 (web) 48 2019 https://doi.org/10.1002/ejic.201900988
HER catalysed by iron complexes without a Fe2S2 core: A review Research Papers in Peer Reviewed Journals Coordination Chemistry Reviews 0010-8545 397 2019 https://doi.org/10.1016/j.ccr.2019.06.019
Dinuclear Manganese Carbonyl Complexes: Electrocatalytic Reduction of Protons to Dihydrogen Research Papers in Peer Reviewed Journals ChemistrySelect 2365-6549 (web) 4 2019 https://doi.org/10.1002/slct.201803754
Nickel (ii) PE 1 CE 2 P pincer complexes (E= O, S) for electrocatalytic proton reduction Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 48 2019 https://doi.org/10.1039/C9DT03626A
A tetranuclear iron complex: substitution with triphenylphosphine ligand and investigation into electrocatalytic proton reduction Research Papers in Peer Reviewed Journals Journal of Chemical Sciences 0973-7103 (web) 130 2018 https://doi.org/10.1007/s12039-018-1529-x
Intramolecular stabilization of a catalytic [FeFe]-hydrogenase mimic investigated by experiment and theory Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 47 2018 https://doi.org/10.1039/C7DT04837H
Study of polyaniline and functionalized ZnO composite film linked through a binding agent for efficient and stable electrochromic applications Research Papers in Peer Reviewed Journals Electrochimica Acta 0013-4686 252 2017 https://doi.org/10.1016/j.electacta.2017.08.144
Synthesis and Electrocatalysis of Diiron Monothiolate Complexes: Small Molecule Mimics of the [FeFe] Hydrogenase Enzyme Research Papers in Peer Reviewed Journals ChemistrySelect 2365-6549 (web) 2 2017 https://doi.org/10.1002/slct.201700084
A mononuclear iron carbonyl complex [Fe (μ-bdt)(CO) 2 (PTA) 2] with bulky phosphine ligands: a model for the [FeFe] hydrogenase enzyme active site with an inverted redox potential Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 46 2017 https://doi.org/10.1039/C7DT01994G
Gd (III)‐DO3A‐SBMPP: An Effort to Develop the MRI Contrast Agent with Enhanced Relaxivity Research Papers in Peer Reviewed Journals ChemistrySelect 2365-6549 (web) 1 2016 https://doi.org/10.1002/slct.201600814
Diiron Complexes [Fe2(CO)5(μ-pdt/Mebdt)(L)] Containing a Chelating Diphosphine Ligand L=(Oxydi-2,1-phenylene)bis(diphenylphosphine): Bioinspired [FeFe] Hydrogenase Model Complexes Research Papers in Peer Reviewed Journals ChemistrySelect 2365-6549 (web) 1 2016 https://doi.org/10.1002/slct.201601216
Diiron benzenedithiolate complexes relevant to the [FeFe] hydrogenase active site Research Papers in Peer Reviewed Journals European Journal of Inorganic Chemistry 1099-0682 (web) 2015 2015 https://doi.org/10.1002/ejic.201500345
Synthesis, characterization and DFT studies of 1, 1′-Bis (diphenylphosphino) ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes Research Papers in Peer Reviewed Journals Journal of Chemical Sciences 0973-7103 (web) 127 2015 https://doi.org/10.1007/s12039-015-0809-y
Hydrogen generation: aromatic dithiolate-bridged metal carbonyl complexes as hydrogenase catalytic site models Research Papers in Peer Reviewed Journals Journal of Inorganic Biochemistry 1873-3344 (web) 143 2015 https://doi.org/10.1016/j.jinorgbio.2014.11.006
[NiFe] hydrogenases: how close do structural and functional mimics approach the active site? Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 43 2014 https://doi.org/10.1039/C4DT00539B
Effect of Cyanide Ligands on the Electronic Structure of [FeFe] Hydrogenase Active-Site Model Complexes with an Azadithiolate Cofactor Research Papers in Peer Reviewed Journals Chemistry- A European Journal E-1521-3765 19 2013 https://doi.org/10.1002/chem.201302467
Microbial hydrogen splitting in the presence of oxygen Research Papers in Peer Reviewed Journals Biochemical Society Transactions E-1470-8752 41 2013 https://doi.org/10.1042/BST20130033
Synthesis, characterization and preclinical evaluation of 1-(3-(4-(318Fluoroprpyl)-1H-1,2,3-Triazol-1-yl)propyl)-4-(2-methoxyphenyl)piperazine as novel D3 receptor ligand for PET imaging Research Papers in Peer Reviewed Journals The Journal of Nuclear Medicine E-2159-662X 54 2013 https://jnm.snmjournals.org/content/54/supplement_2/1074.short "No DOI"
A Model of the [FeFe] Hydrogenase Active Site with a Biologically Relevant Azadithiolate Bridge: A Spectroscopic and Theoretical Investigation Research Papers in Peer Reviewed Journals Angewandte Chemie International Edition E-1521-3773 50 2011 https://doi.org/10.1002/anie.201006244
Catalytic Hydrogen Evolution from Mononuclear Iron(II) Carbonyl Complexes as Minimal Functional Models of the [FeFe] Hydrogenase Active Site Research Papers in Peer Reviewed Journals Angewandte Chemie International Edition E-1521-3773 49 2010 https://doi.org/10.1002/anie.201002719
Valence-State Analysis through Spectroelectrochemistry in a Series of Quinonoid-Bridged Diruthenium Complexes [(acac)2Ru(μ-L)Ru(acac)2]n (n=+2, +1, 0, −1, −2) Research Papers in Peer Reviewed Journals Chemistry- A European Journal E-1521-3765 14 2008 https://doi.org/10.1002/chem.200800976
Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 26 2007 https://doi.org/10.1016/j.poly.2007.03.030
Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex {(μ-tppz)[Ru(bik)Cl]2}3+ (tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2‘-Bis(1-methylimidazolyl)ketone):  EPR Silence, Intervalence Absorption, and νCO Line Broadening Research Papers in Peer Reviewed Journals Inorganic Chemistry 1520-510X (web) 46 2007 https://doi.org/10.1021/ic0700102
Ancillary ligand determination of the spin location in both oxidised and reduced forms of diruthenium complexes bridged by bis-bidentate 1, 4-bis (2-phenolato)-1, 4-diazabutadiene Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 19 2007 https://doi.org/10.1039/B617468J
Tuning intermetallic electronic coupling in polyruthenium systems via molecular architecture Research Papers in Peer Reviewed Journals Journal of Chemical Sciences 0973-7103 (web) 118 2006 https://doi.org/10.1007/BF02703951
An Experimental and Density Functional Theory Approach Towards the Establishment of Preferential Metal- or Ligand-Based Electron-Transfer Processes in Large Quinonoid-Bridged Diruthenium Complexes [{(aap)2Ru}2(μ-BL2–)]n+ (aap = 2-Arylazopyridine) Research Papers in Peer Reviewed Journals European Journal of Inorganic Chemistry 1099-0682 (web) 2006 2006 https://doi.org/10.1002/ejic.200600638
2,2‘-Dipyridylketone (dpk) as Ancillary Acceptor and Reporter Ligand in Complexes [(dpk)(Cl)Ru(μ-tppz)Ru(Cl)(dpk)]n+ where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine Research Papers in Peer Reviewed Journals Inorganic Chemistry 1520-510X (web) 45 2006 https://doi.org/10.1021/ic060887l
2,4,6-Tris(2-pyridyl)-1,3,5-triazine (tptz)-Derived [RuII(tptz)(acac)(CH3CN)]+ and Mixed-Valent [(acac)2RuIII{(μ-tptz-H+)-}RuII(acac)(CH3CN)]+ Research Papers in Peer Reviewed Journals Inorganic Chemistry 1520-510X (web) 45 2006 https://doi.org/10.1021/ic0514288
A New Coordination Mode of the Photometric Reagent Glyoxalbis(2-hydroxyanil) (H2gbha):  Bis-Bidentate Bridging by gbha2- in the Redox Series {(μ-gbha)[Ru(acac)2]2}n (n = −2, −1, 0, +1, +2), Including a Radical-Bridged Diruthenium(III) and a RuIII/RuIV Intermediate Research Papers in Peer Reviewed Journals Inorganic Chemistry 1520-510X (web) 44 2005 https://doi.org/10.1021/ic050950r
2,5-Dioxido-1,4-benzoquinonediimine (H2L2−), A Hydrogen-Bonding Noninnocent Bridging Ligand Related to Aminated Topaquinone: Different Oxidation State Distributions in Complexes [{(bpy)2Ru}2(μ-H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(μ-H2L)]m (m=2−,−,0,+,2+) Research Papers in Peer Reviewed Journals Chemistry-A European Journal 1521-3765 (web) 11 2005 https://doi.org/10.1002/chem.200500202
Sensitive Oxidation State Ambivalence in Unsymmetrical Three-Center (M/Q/M) Systems [(acac)2Ru(μ-Q)Ru(acac)2]n, Q = 1,10-Phenanthroline-5,6-dione or 1,10-Phenanthroline-5,6-diimine (n = +, 0, −, 2−) Research Papers in Peer Reviewed Journals Inorganic Chemistry 1520-510X (web) 44 2005 https://doi.org/10.1021/ic048309x
Tetrazine derived mononuclear RuII(acac)2(L) (1), [RuII(bpy)2(L)](ClO4)2 (2) and [RuII(bpy)(L)2](ClO4)2 (3) (L = 3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine, acac = acetylacetonate, bpy = 2,2′-bipyridine): syntheses, structures, spectra and redox properties Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 24 2005 https://doi.org/10.1016/j.poly.2004.11.019
Isomeric ruthenium terpyridine complexes [Ru(trpy)(L)Cl]n+ containing the unsymmetrically bidentate acceptor L = 3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine. Synthesis, structures, electrochemistry, spectroscopy and DFT calculations Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 2005 2005 https://doi.org/10.1039/B500152H
3,6-Bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L − H+)− as ligands for {(acac)2Run+} or {(bpy)2Rum+}: investigation of mixed valency in [{(acac)2Ru}2(μ-L − H+)]0 and [{(bpy)2Ru}2(μ-L − H+)]4+ by spectroelectrochemistry and EPR Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 2005 2005 https://doi.org/10.1039/B417530A
Isovalent and Mixed-Valent Diruthenium Complexes [(acac)2RuII (μ-bpytz)RuII(acac)2] and [(acac)2RuII(μ-bpytz)RuIII(acac)2](ClO4) (acac = Acetylacetonate and bpytz = 3,6-Bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine):  Synthesis, Spectroelectrochemical, and EPR Investigation Research Papers in Peer Reviewed Journals Inorganic Chemistry 1520-510X (web) 43 2004 https://doi.org/10.1021/ic049346r
{(μ-L)[RuII(acac)2]2}n, n = 2+, +, 0, −, 2−, with L = 3,3′,4,4′-tetraimino-3,3′,4,4′-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 2004 2004 https://doi.org/10.1039/B315927M
The triruthenium complex [{(acac)2RuII}3(L)] containing a conjugated diquinoxaline[2,3-a:2′,3′-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation Research Papers in Peer Reviewed Journals Dalton Transactions 1477-9234 (web) 2004 2004 https://doi.org/10.1039/B316007F
Mononuclear manganese complexes as hydrogen evolving catalysts Research Papers in Peer Reviewed Journals Frontiers in Chemistry 2296-2646 00 2022 https://doi.org/10.3389/fchem.2022.993085
Publications other than journal articles
Title of Publication Type of Publication Publisher Role in Publication ISBN Number Year URL Level
Chapter 7: Hydrogenase biomimetics as catalysts for the hydrogen oxidation reaction (HOR) Chapters in Books Nova Science Publishers, USA Author 978-1-68507-094-6 2021 International
A Closer Look at Coordination Complexes Edited/Transalated Books Nova Science Publishers, USA Editor 978-1-68507-094-6 2021 International
Chapter 10: My husband, son and I: The Three Musketeers Chapters in Books Global Young Academy Co-Author 2020 International
Professional development programmes
Title of the Programme Sponsoring Institution Organising Institution Association as type
Online Faculty Development Program on the Development of Teacher’s e-kit and MOOCs in four quadrant format of e-content Guru Angad Dev Teaching Learning Centre, SGTB Khalsa College, Univ. of Delhi (PMMMNMTT of MHRD) Attending Faculty Development Programmes
Online Faculty Development Programme on "Research Methodology" Teaching Learning Centre, Ramanujan College, Univ. of Delhi (PMMMNMTT of MHRD) Attending Faculty Development Programmes
Seminar / Conference Details / Workshops
Title of the Activity Attended As Date
2-Mercaptobenzimidazole ligand-based models ofthe [FeFe] hydrogenase: Synthesis, characterization and electrochemical studies Poster Presentation 2020-12-19
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