Title Dr. First Name GOPALAIAH Last Name KOVURU
Designation Professor
Department Department of Chemistry
Email gopal@chemistry.du.ac.in
Webpage
Phone.no 9999330689
Employement Info
Employee Type Nature Of Employment
Teaching Permanent
Teaching experience inside the Institution
Designation Institution Duration From Duration To
Post-doctoral Researcher Universite de Paris Sud, France 2006-05-01 2007-04-30
Post-doctoral Researcher Universite de Paris Sud, France 2007-09-01 2008-08-31
Assistant Professor University of Delhi 2010-07-08 2020-07-08
Associate Professor University of Delhi 2020-07-08 2022-09-15
Administrative experience outside the Institution
Designation Institution Name Duration from Duration to
Associate Research Scientist AstraZeneca India Private Limited 2009-01-07 2010-03-30
Research Guidance
PhD scholars under Supervision Awarded PhD Submitted
1 5
Research Publications
Article Name Publication Type Journal Name ISSN No Volume Year URL DOI
Justicia lignans: Part 9† ‒ Two new lignans from Justicia neesii Ramamoorthy (white flower variety) Research Papers in Peer Reviewed Journals Indian Journal of Chemistry 0376-4699 40B 2001 No DOI

Beckmann Rearrangementin the Solid State: Reactionof Oxime Hydrochlorides Research Papers in Peer Reviewed Journals Tetrahedron Letters 0040-4039 42 2001 doi.org/10.1016/S0040-4039(01)01737-3

Beckmann Rearrangement of Ketoximes on Solid Metaboric Acid: A Simple and Effective Procedure Research Papers in Peer Reviewed Journals Tetrahedron Letters 0040-4039 43 2002 doi.org/10.1016/S0040-4039(02)00282-4

Effective ‘Non-Aqueous Hydrolysis’ of Oximes with Iodic Acid in Dichloromethane under Mild, Heterogeneous Conditions Research Papers in Peer Reviewed Journals Tetrahedron Letters 0040-4039 43 2002 doi.org/10.1016/S0040-4039(02)00710-4

Juspurpurin, an Unusual Secolignan Glycoside from Justicia Purpurea Research Papers in Peer Reviewed Journals Journal of Natural Products 0163-3864 66 2003 doi.org/10.1021/np030142h

Beckmann Reaction of Oximes Catalysed by Chloral: Mild and Neutral Procedures Research Papers in Peer Reviewed Journals Tetrahedron Letters 0040-4039 44 2003 doi.org/10.1016/S0040-4039(02)02644-8

Ketones to Amides via a Formal Beckmann Rearrangement in ‘One Pot’: A Solvent-Free Reaction Promoted by Anhydrous Oxalic Acid. Possible Analogy with the Schmidt Reaction Research Papers in Peer Reviewed Journals Tetrahedron Letters 0040-4039 44 2003 doi.org/10.1016/j.tetlet.2003.08.038

Oxalic Acid: A Very Useful Brønsted Acid in Organic Synthesis Research Papers in Peer Reviewed Journals Synlett 0936-5214 2004 DOI: 10.1055/s-2004-836028

A Simple and Effective Glycine-Catalysed Procedure for the Preparation of Oximes Research Papers in Peer Reviewed Journals Journal of Chemical Research 1747-5198 2006 doi.org/10.3184/030823406777946770

The Generalized Anomeric Effect in the 1,3-Thiazolidines: Evidence for Both Sulphur and Nitrogen as Electron Donors. Crystal Structures of Various N-Acylthi- azolidines Including Mercury(II) Complexes. Possible Relevance to Penicillin Action Research Papers in Peer Reviewed Journals Journal of Molecular Structure 0022-2860 837 2007 doi.org/10.1016/j.molstruc.2006.10.034

Use of Samarium Diiodide in the Field of Asymmetric Synthesis Research Papers in Peer Reviewed Journals New Journal of Chemistry 1144-0546 32 2008 doi.org/10.1039/B718330P

Equilibrium of Homochiral Oligomerization of a Mixture of Enantiomers. Its Relevance to Nonlinear Effects in Asymmetric Catalysis Research Papers in Peer Reviewed Journals Journal of Physical Chemistry B 1520-6106 112 2008 doi.org/10.1021/jp8058917

Early History of Asymmetric Synthesis: Who Are the Scientists Who Set Up the Basic Principles and the First Experiments ? Research Papers in Peer Reviewed Journals New Journal of Chemistry 1144-0546 35 2011 doi.org/10.1039/C1NJ20216B

Use of Nonfunctionalized Enamides and Enecarbamates in Asymmetric Synthesis Research Papers in Peer Reviewed Journals Chemical Reviews 0009-2665 111 2011 doi.org/10.1021/cr100031f

Recent Developments in Samarium Diiodide Promoted Organic Reactions Research Papers in Peer Reviewed Journals Chemical Record 1527-8999 13 2013 doi.org/10.1002/tcr.201200028

Chiral Iron Catalysts for Asymmetric Synthesis Research Papers in Peer Reviewed Journals Chemical Reviews 0009-2665 113 2013 doi.org/10.1021/cr300236r

Anion (Fluoride)-Doped Ceria Nanocrystals: Synthesis, Characterization, and its Catalytic Application to Oxidative Coupling of Benzylamines Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 53 2014 doi.org/10.1021/ic403166q

Iron(II) Bromide-Catalyzed Oxidative Coupling of Benzylamines with ortho- Substituted Anilines: Synthesis of 1,3-Benzazoles Research Papers in Peer Reviewed Journals RSC Advances 2046-2069 5 2015 doi.org/10.1039/C4RA12490A

Iron-Catalyzed Oxidative Coupling of Benzylamines and Indoles: Novel Approach for Synthesis of Bis(indolyl)methanes Research Papers in Peer Reviewed Journals Synthesis 0039-7881 47 2015 DOI: 10.1055/s-0034-1380012

A Solvent-Free Process for Synthesis of Imines by Iron-Catalyzed Oxidative Self- or Cross-Condensation of Primary Amines Using Molecular Oxygen as Sole Oxidant Research Papers in Peer Reviewed Journals Catalysis Letters 1011-372X 146 2016 DOI 10.1007/s10562-016-1789-3

Growth, Crystal Structure, Hirshfeld Surface, Optical, Piezoelectric, Dielectric and Mechanical Properties of Bis(L-Asparaginium Hydrogensquarate) Single Crystal Research Papers in Peer Reviewed Journals Acta Crystallographica 2052-5206 B73 2017 DOI: 10.1107/S2052520617002906

Copper-Catalyzed Aerobic Oxidative Coupling of o-Phenylenediamines with 2- Aryl/Heteroarylethylamines: Direct Access to Construct Quinoxalines Research Papers in Peer Reviewed Journals Organic and Biomolecular Chemistry 1477-0520 15 2017 DOI: 10.1039/C7OB00122C

Iron-Catalyzed Cascade Reaction of 2-Aminobenzyl Alcohols with Benzylamines: Synthesis of Quinazolines by Trapping of Ammonia Research Papers in Peer Reviewed Journals Organic and Biomolecular Chemistry 1477-0520 15 2017 doi.org/10.1039/C7OB01159H

An Insight into the Synthesis, Crystal Structure, Geometrical Modelling of Crystal Morphology, Hirshfeld Surface Analysis and Characterization of N-(4-Methylbenzyl) benzamide Single Crystals Research Papers in Peer Reviewed Journals Journal of Applied Crystallography 0021-8898 50 2017 doi.org/10.1107/S1600576717012316

Iron-Catalyzed Aerobic Oxidative Cleavage and Construction of C-N Bonds: A Facile Method for Synthesis of 2,4,6-Trisubstituted Pyridines Research Papers in Peer Reviewed Journals Asian Journal of Organic Chemistry 2193-5807 7 2018 doi.org/10.1002/ajoc.201800312

Straightforward Access to 3,4-Dihydro-2H-1,2,4-benzothiadiazine 1,1-dioxides and Quinazolines via Iron-Catalyzed Aerobic Oxidative Condensation of Amines Research Papers in Peer Reviewed Journals ChemistrySelect 2365-6549 4 2019 doi.org/10.1002/slct.201900850

Synthesis of (E)-3-Alkylideneindolin-2-ones by an Iron-Catalyzed Aerobic Oxidative Condensation of Csp3–H Bonds of Oxindoles and Benzylamines Research Papers in Peer Reviewed Journals European Journal of Organic Chemistry 1434-193X 2020 doi.org/10.1002/ejoc.202001300

Microspherical core-shell MoO2-graphitic C3N4 heterojunction promoted integration leading to Krӧhnke pyridines and degradation of xylenol orange Research Papers in Peer Reviewed Journals Materials Today Communications 2352-4928 26 2021 doi.org/10.1016/j.mtcomm.2021.102117

Synthesis of Kröhnke Pyridines through Iron-Catalyzed Oxidative Condensation/Double Alkynylation/Amination Cascade Strategy Research Papers in Peer Reviewed Journals Tetrahedron 0040-4020 98 2021 doi.org/10.1016/j.tet.2021.132429

Research Projects
Title of the Project Project Type Year Of Sanction Output Start Date End Date
Novel C2-Symmetric Chiral Bisimidazolineand Bisoxazoline Ligands for AsymmetricCatalysis 2010 2010-08-23 2011-02-15
Development of Novel Iron Catalysts forHydrogenation with Molecular Hydrogen orTransfer Hydrogenation 2011 2011-06-16 2012-02-15
Development of Chiral Metal Complexes Using Privileged Ligands for Asymmetric Synthesis 2012 2012-07-03 2013-02-15
Oxidative Coupling Reactions of Benzylamines to Prepare Bioactive Heterocycles 2013 2013-10-21 2014-03-15
Samarium(II) Iodide-Mediated Cross-Coupling Reactions 2014 2014-10-15 2015-09-30
Iron-Catalyzed Coupling Reactions for the Synthesis of 1,3-Benzazoles 2015 2015-01-06 2015-03-31
Novel Approaches for the Synthesis of Quinoxalines and Bis(indolyl)methanes 2015 2015-10-15 2016-10-15
Synthesis of Nitrogen-Containing Heterocyclic Compounds using Transition Metal Catalysts 2016 2016-06-24 2016-09-30
Synthesis of 3,4-dihydro-2H-1,2,4-benzothiadiazine 1,1-dioxides 2018 2018-08-20 2018-12-31
Sustainable Metal-Catalyed Oxidative Tandem Reactions: Exploring Novel Approaches for Synthesis of Biologically Relevant Nitrogen-Containing Heterocycles 2018 2018-06-01 2021-05-31
Transition Metal-Catalyzed Cascade Oxidative Reactions for the Synthesis of Nitrogen Heterocycles 2020 2020-12-31 2021-03-15
Development of Novel Oxidative Methods for the Construction of Biologically Potent Acridine Alkaloids and Related Molecules 2021 2021-10-29 2022-03-15
Professional development programmes
Title of the Programme Sponsoring Institution Organising Institution Association as type
Research Methodology: Tools & Techniques ARSD College, University of Delhi Attending Faculty Development Programmes
Refresher Course in Chemistry Centre for Professional Development in Higher Education (CPDHE), University of Delhi Attending Refresher Program
Refresher Course in Chemistry Human ResourceDevelopment Centre (HRDC), Jawaharlal Nehru Technological University Hyderabad Attending Refresher Program
Refresher Course in Chemistry Centre for ProfessionalDevelopment in Higher Education (CPDHE), University of Delhi Attending Refresher Program
Orientation Programme OR-74 University of Delhi Centre forProfessional Development in Higher Education (CPDHE), University of Delhi Attending Orientation Programme
Honour And Awards
Name of the Award Name of the Awarding Body Award Category Level Date of Award
Prof. Sudheer K. Banerjee Memorial Award Indian Council of Chemists Research National 2014-12-17
Prof. D. Bhaskar Reddy Excellence Award Sri Venkateswara University Research State/University Level 2016-03-29
ISCAS Dr. Lakshmi Endowment Medal Indian Association of Solid State Chemists and Allied Scientists Research National 2019-12-20
Patents
Patent Title Outcome of the Patent Patent Number Level of Patent
An Anti-Hypertensive Cardio-Protective Composition IN201811005899 National
Seminar / Conference Details / Workshops
Title of the Activity Attended As Date
The Saga of Nobel and Wolf Prizes of theYear 2001 in Catalytic Asymmetric Synthesis Invited Talk 2010-11-26
Use of Non-Functionalized Enamides inAsymmetric Synthesis Invited Talk 2010-12-23
Role of Non-Functionalized Enecarbamates inAsymmetric Synthesis Invited Talk 2011-01-30
Carbon-Carbon and Carbon-Nitrogen BondFormations by Oxidative Coupling Strategy Invited Talk 2011-11-28
Use of Chiral Iron Catalysts for AsymmetricSynthesis Invited Talk 2013-12-04
Enantioselective Iron- Catalyzed Reactions Invited Talk 2014-12-15
Iron-Catalyzed Oxidative Condensation ofIndoles and Benzylamines Invited Talk 2015-04-11
Novel Approaches for the Synthesis of Nitrogen-Heterocycles Using Sustainable Metal Catalysts Invited Talk 2015-05-08
Oxidative Condensation of Benzylamines with o-Substituted Anilines Invited Talk 2015-09-14
Oxidative Coupling Reactions of PrimaryAmines Invited Talk 2015-11-23
Oxidative Coupling Reactions of Amines Using Iron-Catalysts Invited Talk 2015-12-16
Synthesis of Biologically Relevant Five and Six-Membered Heterocyclic Compounds Invited Talk 2015-12-26
Synthesis of Nitrogen-Heterocycles by Oxidative Coupling Methods Invited Talk 2016-03-28
Iron-Catalyzed Oxidative Coupling Reactions: Novel Approaches to Nitrogen Heterocycles Invited Talk 2016-10-21
Sustainable Metal-Catalyzed Aerobic Oxidative Transformations for Synthesis of Nitrogen-Heterocycles Invited Talk 2017-07-01
Bond Formations between Two Nucleophiles: Sustainable Metal-Catalyzed Oxidative Reactions Invited Talk 2017-12-26
Construction of Bioactive N-Heterocycles by Transition Metal-Catalyzed Oxidative Reactions Invited Talk 2019-03-02
Construction of N-Heterocycles by Sustainable Metal-Catalyzed Oxidative Annulation Reactions Invited Talk 2019-03-29
Synthesis of Biologically Active N-Heterocycles via Iron-Catalyzed Cascade Oxidative Condensation and Annulation Invited Talk 2019-12-20
Metal-Catalyzed Aerobic Oxidative Tandem Reactions for the Synthesis of Biologically Relevant Heterocycles Invited Talk 2021-08-11
Oxidative Coupling and Annulation Strategies for the Construction of Privileged N-Heterocycles Invited Talk 2021-12-29
Synthesis of Pyridine Derivatives and their Luminescent Properties Invited Talk 2022-01-07
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