Title Prof. First Name THIRUPATHI Last Name NATESAN
Designation Senior Professor
Department Department of Chemistry
Email tnat@chmistry.du.ac.in
Webpage
Phone.no 9818465378
Employement Info
Employee Type Nature Of Employment
Teaching Permanent
Educational
Degree/Certification Institution Year
Ph.D. - Contributions to the chemistry of cyclotriphosphazanes and bicyclic tertraphosphapentazanes Indian Institute of Science 1998
PG University of Madras 1991
Qualifications
Examination Name Conducted By Date of Passing
NET Council of Scientific and Industrial Research 1991-10-15
Teaching experience inside the Institution
Designation Institution Duration From Duration To
Research Associate Indian Institute of Science 1997-01-01 1998-07-01
Postdoctoral Fellow University of Ottawa 1998-08-01 1999-09-30
Postdoctoral Fellow Iowa State University 1999-10-01 2002-09-30
Postdoctoral Fellow Case Western Reserve University 2002-10-01 2003-12-31
Reader University of Delhi 2004-02-09 2007-02-09
Associate Professor University of Delhi 2007-02-10 2010-02-09
Professor University of Delhi 2010-04-01 2020-04-01
Senior Professor University of Delhi 2020-04-01 2023-01-07
Administrative experience within Institution
Designation Institution Name Duration from Duration to
Joint Director University of Delhi 2021-10-04 2023-10-04
Research Guidance
PhD scholars under Supervision Awarded PhD Submitted
15
M.Phil Scholars – Under Supervision Awarded Degree Submitted
4
Research Publications
Article Name Publication Type Journal Name ISSN No Volume Year URL DOI
Cobalt(II)-Catalyzed Directed C–H Functionalization/[3+2] Annulation of N-Arylguanidines with Alkynes Research Papers in Peer Reviewed Journals Organic Letters 1523-7052 24 2022 https://pubs.acs.org/journal/orlef7 doi.org/10.1021/acs.orglett.2c02503
Palladium(II) Pincer Complexes Derived From N,N’,N’’-Tris(2-thioanisyl)guanidine. Syntheses, Structural Aspects, Solution Behaviour and Suzuki-Miyaura Coupling Reactions Research Papers in Peer Reviewed Journals ChemistrySelect 2365-6549 7 2022 https://chemistry-europe.onlinelibrary.wiley.com/journal/23656549 doi.org/10.1002/slct.202202778
Reactivity studies of cycloplatinated triarylguanidinato complexes, [Pt(TAG-κC,κN)(X)(S(O)Me2)] (X = Cl and OC(O)CF3) towards Lewis bases, and structural aspects of the products Research Papers in Peer Reviewed Journals Journal of Organometallic Chemistry 0022-328X 959 2022 https://www.sciencedirect.com/journal/journal-of-organometallic-chemistry doi.org/10.1016/j.jorganchem.2021.122200
[6,5] CNN Palladium(II) Pincer Complexes Containing N-Substituted Monoanionic and Dianionic Guanidinate Ligands: Syntheses, Structural Aspects, and Their Utility in Suzuki–Miyaura Coupling Reactions Research Papers in Peer Reviewed Journals Organometallics 0276-7333 40 2021 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/acs.organomet.1c00414
Reactions of Cycloplatinated Guanidine Complexes with Hg(OC(O)CF3)2: Formation of a One-Dimensional Coordination Polymer Containing a Pt2Hg(μ2-S(O)Me2-S,O) Repeating Unit versus a Discrete Pt2Hg2 Complex Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 60 2021 https://pubs.acs.org/journal/inocaj doi.org/10.1021/acs.inorgchem.0c03674
Unusual [Pt{κ2(C,N)}]+ → [Pt{κ2(N,N)}]+ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic N,N′,N″-Tris(3,5-xylyl)guanidinatoplatinum(II) Bis(phosphine) Complexes. Syntheses, Structural and Theoretical Studies Research Papers in Peer Reviewed Journals Organometallics 0276-7333 39 2020 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/acs.organomet.0c00408
Syntheses and structural aspects of dinuclear cycloplatinated N,N′,N″-triarylguanidinate(2−) complexes with a novel tridentate μ2-κ2(C,N):κ1N coordination mode Research Papers in Peer Reviewed Journals Journal of Organometallic Chemistry 0022-328X 911 2020 https://www.sciencedirect.com/journal/journal-of-organometallic-chemistry doi.org/10.1016/j.jorganchem.2020.121138
Half Sandwich Electron Deficient N,N′,N′′-Triarylguanidinatoruthenium(II) Complexes: Syntheses, Reactivity Studies, and Structural Aspects Research Papers in Peer Reviewed Journals European Journal of Inorganic Chemistry 1099-0682 2019 2019 https://chemistry-europe.onlinelibrary.wiley.com/journal/10990682c doi.org/10.1002/ejic.201900616
Homoleptic cis- and trans-palladium(II) bis(guanidinato) complexes derived from N-aryl-N′,N″-di(pyridin-2-yl)- and N-aryl-N′,N″-bis(6-methylpyridin-2-yl)guanidines: Catalysts for Heck-Mizoroki coupling reactions Research Papers in Peer Reviewed Journals Journal of Organometallic Chemistry 0022-328X 892 2019 https://www.sciencedirect.com/journal/journal-of-organometallic-chemistry doi.org/10.1016/j.jorganchem.2019.04.009
Influence of cadmium(II) source upon the formation of a discrete monomer [Cd(κ2-OC(O)tBu)2(H2O)2] and a trinuclear heterobimetallic 1D CP, {Na2[Cd(μ5-κ3:κ3-OAc)(μ3-κ2:κ3-OC(O)tBu)(μ3-κ1:κ2-OC(O)tBu)2]·2tBuC(O)OH}∞ Research Papers in Peer Reviewed Journals Inorganica Chimica Acta 1873-3255 489 2019 https://www.sciencedirect.com/journal/inorganica-chimica-acta doi.org/10.1016/j.ica.2019.02.012
Syntheses and structural aspects of six-membered palladacyclic complexes derived from N,N′,N′′-triarylguanidines with N- or S-thiocyanate ligand Research Papers in Peer Reviewed Journals New Journal of Chemistry 1369-9261 43 2018 https://www.rsc.org/journals-books-databases/about-journals/njc doi.org/10.1039/C8NJ04167A
Syntheses, characterization, solution behavior and catalytic activity of trans-[(guanidine)2PdX2] (X = Cl and OC(O)R; R = Me, Ph and tBu) in Heck–Mizoroki coupling reactions involving chloroarenes/methyl acrylate Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 151 2018 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2018.05.022
Critical Role of Anions in Platinum(II) Precursors upon the Structural Motifs of Six-Membered Cycloplatinated N,N′,N″-Triarylguanidines Research Papers in Peer Reviewed Journals ACS Omega 2470-1343 3 2018 https://pubs.acs.org/journal/acsodf doi.org/10.1021/acsomega.8b00782
Probing the factors that influence the conformation of a guanidinato ligand in [(η5-C5Me5)M(NN)X] (NN = chelating N,N′,N′′-tri(o-substituted aryl)guanidinate(1−); X = chloro, azido and triazolato) Research Papers in Peer Reviewed Journals New Journal of Chemistry 1369-9261 42 2017 https://www.rsc.org/journals-books-databases/about-journals/njc doi.org/10.1039/C7NJ03766J
Syntheses, characterisation, and catalytic role of (η5-C5Me5)Rh(iii) guanidinato complexes in transfer hydrogenation (TH) and TH–etherification Research Papers in Peer Reviewed Journals RSC Advances 7 2017 https://www.rsc.org/journals-books-databases/about-journals/rsc-advances/ doi.org/10.1039/C7RA04152G
Syntheses, Structural Aspects, Solution Behavior, and Catalytic Utility of Cyclopalladated N,N′,N″-Triarylguanidines [κ2(C,N))Pd(Pyrazole)2X] (X = Br, OC(O)CF3, and PF6) in Suzuki–Miyaura Coupling Reactions of Aryl Bromides Research Papers in Peer Reviewed Journals Organometallics 1520-6041 35 2016 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/acs.organomet.6b00442
Six-membered cyclopalladated N,N′,N″-triarylguanidines, [{κ2(C,N)Pd}2(μ-OAc)(μ-Pz)], [κ2(C,N)Pd(μ-Pz)]2 and a novel [AgNO3⊂{{κ2(C,N)Pd}2(μ-NO3)(μ-Pz)}]: Syntheses, reactivity studies, structural aspects, and solution behavior Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 117 2016 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2016.07.008
Ionic and Neutral Half-Sandwich Guanidinatoruthenium(II) Complexes and Their Solution Behavior Research Papers in Peer Reviewed Journals European Journal of Inorganic Chemistry 1099-0682 2015 2015 https://chemistry-europe.onlinelibrary.wiley.com/journal/10990682c doi.org/10.1002/ejic.201500395
Reactions of Cd(OAc)2·2H2O with variously substituted pyridines. Efforts to unravel the factors that determine structure/nuclearity of the products Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 98 2015 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2015.06.002
Depalladation of Neutral Monoalkyne- and Dialkyne-Inserted Palladacycles and Alkyne Insertion/Depalladation Reactions of Cationic Palladacycles Derived from N,N′,N″-Triarylguanidines as Facile Routes for Guanidine-Containing Heterocycles/Carbocycles: Synthetic, Structural, and Mechanistic Aspects Research Papers in Peer Reviewed Journals Organometallics 33 2014 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om500837v
Insertion Reactions of Six-Membered Cyclopalladated N,N′,N″-Triarylguanidine, [Pd{κ2(C,N)-C6H3Me-3(NHC(NHAr)(═NAr))-2}(μ-Br)]2 (Ar = 2-MeC6H4) with PhC≡C—C(O)OR (R = Me and Et): A Gateway to Second Orthopalladation through Novel Rearrangements Research Papers in Peer Reviewed Journals Organometallics 1520-6041 32 2013 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om4010719
Six-membered [C,N] cyclopalladated sym N,N′,N″-tri(4-tolyl)guanidines: Synthesis, reactivity studies and structural aspects Research Papers in Peer Reviewed Journals Journal of Organometallic Chemistry 0022-328X 741-742 2013 https://www.sciencedirect.com/journal/journal-of-organometallic-chemistry doi.org/10.1016/j.jorganchem.2013.05.030
Mole Ratio Dependent Formation of Mononuclear versus Pentanuclear Zinc(II) Pivalate Complexes and the 'Carboxylate Shift' Process. Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 55 2013 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2013.02.081
Dual Role of Acetate as a Nucleophile and as an Internal Base in Cycloplatination Reaction of sym-N,N′,N″-Triarylguanidines Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 2013 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic302058u
Influence of Steric Effect on the Structural Aspects of N,N',N''-Triarylguanidine Derived Six-Membered [C,N] Palladacycles. Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 52 2013 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2012.06.077
Synthesis, Reactivity Studies, Structural Aspects, and Solution Behavior of Half Sandwich Ruthenium(II) N,N',N''-Triarylguanidinate Complexes. Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 51 2012 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic201343w
3,5-Lutidine coordinated zinc(II) aryl carboxylate complexes: Precursors for zinc(II) oxide Research Papers in Peer Reviewed Journals Inorganica Chimica Acta 0020-1693 372 2011 https://www.sciencedirect.com/journal/inorganica-chimica-acta doi.org/10.1016/j.ica.2011.01.083
Effects of steric/basic properties of Lewis bases on the degree of aggregation of zinc(II) pivalate complexes Research Papers in Peer Reviewed Journals Inorganica Chimica Acta 0020-1693 370 2011 https://www.sciencedirect.com/journal/inorganica-chimica-acta doi.org/10.1016/j.ica.2011.01.040
Synthesis, Reactivity, Structural Aspects, and Solution Dynamics of Cyclopalladated Compounds of N,N′,N′′-Tris(2-anisyl)guanidine Research Papers in Peer Reviewed Journals Organometallics 1520-6041 30 2011 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om1009445
Synthesis and Conformational Features of Sym N,N',N''-Triarylguanidines. Research Papers in Peer Reviewed Journals Journal of Chemical Sciences 0973-7103 122 2010 https://www.springer.com/journal/12039/ doi.org/10.1007/s12039-010-0017-8
Factors Dictating the Nuclearity/Aggregation and Acetate Coordination Modes of Lutidine-Coordinated Zinc(II) Acetate Complexes. Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 49 2009 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic901100z
Latent cationic palladium(II) phosphine carboxylate complexes for norbornene polymerization Research Papers in Peer Reviewed Journals Journal of Polymer Science Part A: Polymer Chemistry 0887624X, 10990518 47 2009 https://onlinelibrary.wiley.com/journal/26424169 doi.org/10.1002/pola.23125
Comparisons of Phosphorus Ligation Properties in P(CH2NR)3P. Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 46 2007 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic0703070
Reactivity Studies of Cationic Palladium(II) Phosphine Carboxylate Complexes with Lewis Bases: Substitution versus Cyclometalation. Research Papers in Peer Reviewed Journals Organometallics 1520-6041 26 2007 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om070069g
Synthesis and Photoelectron Spectroscopic Studies of N(CH2CH2NMe)3PE (E = O, S, NH, CH2) Research Papers in Peer Reviewed Journals Journal of the American Chemical Society 0002-7863 128 2006 https://pubs.acs.org/journal/jacsat doi.org/10.1021/ja0547533
Synthesis and Reactivity of Cationic Palladium Phosphine Carboxylate Complexes. Research Papers in Peer Reviewed Journals Organometallics 1520-6041 24 2005 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om050356p
An Investigation of Staudinger Reactions Involving Cis-1,3,5-Triazidocyclohexane and Tri(alkylamino)phosphines. Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 43 2004 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic0492845
Reactions of Tris(amino)phosphines with Arylsulfonyl Azides:  Product Dependency on Tris(amino)phosphine Structure Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 42 2002 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic025920s
Mono- and Dianionic Guanidinate Ligands. Reactivity of [iPrN:C(NiPr)2]Ta(NMe2)3 and [(iPrNH)C(NiPr)2]TaCl(NMe2)3 with Me3SiCl and ArNC (Ar = 2,6-Me2C6H4). Research Papers in Peer Reviewed Journals Organometallics 1520-6041 19 2000 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om991010f
Group 5 Transition Metal Imido Complexes with Dianionic Guanidinate Ligands Displaying Extended Interactions. Research Papers in Peer Reviewed Journals Chemical Communications 1364-548X 1999 1999 https://www.rsc.org/journals-books-databases/about-journals/chemcomm/ doi.org/10.1039/A906976C
Cyclotriphosphazanes and Bicyclic Tetraphosphapentazanes Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 1042-6507 144-146 1999 https://www.tandfonline.com/journals/gpss20 doi.org/10.1080/10426509908546232
Guanidinate Anions and Dianions. Reactions Involving Alkylguanidines, (RNH)2CNR (R = i-Pr or Cy), Metal Amido Complexes M(NMe2)5 (M = Ta or Nb). Research Papers in Peer Reviewed Journals Journal of Chemical Society, Dalton Transactions 1477-9234 1999 1999 https://pubs.rsc.org/en/journals/journalissues/dt#!recentarticles&adv doi.org/10.1039/A904072B
Oxidative Addition of Tetrachloro-1,2-benzoquinone to λ3-Cyclotriphosphazanes. An Unusual Ring Contraction−Rearrangement Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 38 1999 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic980459i
Molybdenum tetracarbonyl complexes of (aryloxy) λ3-cyclotriphosphazanes; X-ray crystal structure of [Mo(CO)4{EtNP(OC6H4Br-4)}3] Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 18 1988 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/S0277-5387(98)00315-5
CONFORMATIONS OF (ARYLOXY)-δ3-CY CLOTRIPHOSPHAZANES. SINGLE CRYSTAL X-RAY STRUCTURES OF [EtNP(OR)]3 [R=C6H4Br-2 (CIS), C6H3Me2-2,6 (TRANS)] Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 1563-5325 123 1997 https://www.tandfonline.com/journals/gpss20 doi.org/10.1080/10426509708044215
Synthesis, reactivity and structural characterisation of bicyclic tetraphosphapentazanes Research Papers in Peer Reviewed Journals Journal of Chemical Society, Dalton Transactions 1477-9234 1998 1998 https://pubs.rsc.org/en/journals/journalissues/dt#!recentarticles&adv doi.org/10.1039/A801443D
The Reaction of λ3-Cyclotriphosphazanes with Tetrachloro-o-benzoquinone: an Unusual Ring Contraction-Rearrangement. Research Papers in Peer Reviewed Journals Chemical Communications 1364-548X 1996 1996 https://www.rsc.org/journals-books-databases/about-journals/chemcomm/ doi.org/10.1039/CC9960001703
Preparation, spectral characterization, and single crystal X-ray structures of cis and trans isomers of 2,4,6-trifluoroethoxy-1,3,5-triethyl-1,3,5,2λ5, 4λ5, 6λ5-triazatriphosphorinane-2,4,6-trioxide, [ETNP(O)(OCH2CF3)]3 Research Papers in Peer Reviewed Journals Heteroatom Chemistry 10427163, 10981071 6 1995 https://www.hindawi.com/journals/htrc/ doi.org/10.1002/hc.520060114
New Insights into the Chemistry of Cyclic Phosphorus-Nitrogen Compounds. Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 10426507, 15635325. 93-94 1994 https://www.tandfonline.com/journals/gpss20 doi.org/10.1080/10426509408021821
Mono- and Dialkyne Insertion Reactions of Cyclopalladated N,N′,N″-Triarylguanidines [κ2(C,N)Pd(μ-Br)]2 and cis-/trans-[κ2(C,N)Pd(Lewis Base)Br]. Scaffolds for Enlarged, Rearranged, and Zwitterionic Palladacycles through Ring Contraction cum Amine–Imine Tautomerization Research Papers in Peer Reviewed Journals Organometallics 1520-6041 33 2014 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om500423q
Influence of the Steric/Electronic Properties of N-Aryl Substituents in Cycloplatinated Guanidinate(1−) Complexes on the Formation of Discrete Pt → Ag Complexes and One-Dimensional Coordination Polymer Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 62 2023 https://pubs.acs.org/journal/inocaj doi.org/10.1021/acs.inorgchem.2c04172
Palladium(II) complexes derived from N,N’− diarylthiourea: Structural aspects and applications toward Suzuki-Miyaura coupling reactions Research Papers in Peer Reviewed Journals Journal of Molecular Structure 0022-2860 1288 2023 https://www.sciencedirect.com/journal/journal-of-molecular-structure doi.org/10.1016/j.molstruc.2023.135797
Efforts to understand the degree of carboxylate substitution in cis-[Pt(S(O)Me2)(guanidine)Cl2]: Synthetic, Structural and DFT Studies Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 247 2024 https://www.sciencedirect.com/journal/polyhedron https://doi.org/10.1016/j.poly.2023.116735
Publications other than journal articles
Title of Publication Type of Publication Publisher Role in Publication ISBN Number Year URL Level
SINGLE COMPONENT CATIONIC PALLADIUM PROINITIATORS FOR THE LATENT POLYMERIZATION OF CYCLOOLEFNS Full Paper in Conference Proceedings/Other United States Patent Application Publication Co-Author 10/976,350 2004 https://patents.justia.com/inventor/natesan-thirupathi International
Research Projects
Title of the Project Project Type Year Of Sanction Output Start Date End Date
Cobalt(II) Catalyzed Directed C-H Functionalization of N-Substituted Guanidines with 1,3-Diynes Minor 2022 The outcome was published in the form of poster in the conference and published as a paper. 2022-09-01 2023-02-15
Guanidine containing heterocycles through domino reactions involving N-aryl guanidines and alkynes/1,3-diynes and allenes using cobalt(II) catalysts Minor 2020 The outcome was published in the form of poster in the conference and published as a paper. 2020-01-01 2021-03-15
Cobalt(II) Catalyzed Directed C-H Activation Reactions of N-Substituted Guanidines with 1,3-Diynes and Allenes Minor 2021 The outcome was published in the form of poster in the conference and published as a paper. 2021-09-29 2022-03-15
sym N,N′,N″-Triarylguanidines as Scaffolds for New Class of Metallacycles and Half Sandwich Complexes of Platinum Group Metals Major 2015 The outcome of the project was published in the form of more than 10 publications and presented in the form of poster and invited talk in several conferences 2015-09-09 2019-03-08
N,N',N"–Triarylguanidine complexes of platinum metal groups Major 2010 The outcome of the project was presented in several conferences and published in peer reviewed journals. 2010-04-22 2013-10-22
Platinum Group metal complexes on N,N',N"–Triarylguanidines Major 2016 The outcome of the project is presented in several conferences and published in peer reviewed journals. 2016-06-24 2019-06-24
Lewis base supported zinc(II) carboxylate complexes and their thermal behaviour Major 2006 The outcome of the project was presented in several conferences and published in peer reviewed journals. 2006-11-02 2010-06-03
Guanidine Scaffold for constructing short and wide bite angle phosphine ligands and their transition metal complexes Major 2005 The outcome of the project was presented in several conference and published in peer reviewed journals. 2005-01-17 2008-07-18
Professional development programmes
Title of the Programme Sponsoring Institution Organising Institution Association as type
UGC-Sponsored Refresher Course University Grant Comission University of Delhi Organising Refresher Program
Seminar / Conference Details / Workshops
Title of the Activity Attended As Date
Palladium(II) and platinum(II) complexes of N,N',N"-triarylguanidines. Recent findings and ongoing investigations Oral Presentation 2018-10-28
Organo-Platinum and -Plalladium Complexes of N-Arylguanidines Invited Talk 2022-12-15
Synthesis, structural and optical studies of six-membered cycloplatinated guanidines, [Pt{k2(C,N)}{k2(O,O'-acac)}] Poster Presentation 2018-10-28
Reactivity studies of six-membered cycloplatinated guanidines, [Pt{k2(C,N)}(OC(O)CF3)(DMSO)] with Ph2P(CH2)nPPh2 (n = 1-3). Efforts to unravel factors that determine C,N versus N,N coordination modes of N,N',N"-triarylguanidines in the products Poster Presentation 2018-10-28
Formation of mono- and dinuclear palladium pincers derived from picolinamide and picolyl protected unsymmetrical N,N’,N”-trisubstituted guanidines and their role as catalysts in Suzuki-Miyaura coupling reactions. Poster Presentation 2019-12-11
Syntheses of indole N-carboximidamides from unsymmetrical N,N',N"-triarylguanidines through cobalt (II) catalysed directed C-H activation Poster Presentation 2019-12-11
Platinum(II) adducts, cis-[L2PtXX'] (X = X' = Cl (1); X = Cl, X' = OC(O)CH3 (2) and X = X' = OC(O)CF3 (3)) of rigid 2-amino benzimidazole type guanidines, L. Synthetic and structural studies. Poster Presentation 2019-12-11
CNN Palladium(II) Pincer Complexes Derived from Picolyl Based N-Substituted Guanidines. Syntheses, Structures, Reactivity and Catalytic Activity in Cycloisomerisation of 4-pentynoic Acid Poster Presentation 2021-09-26
Cobalt(II) Catalysed Directed C-H Activation/Annulation of N-Arylguanidines with Internal Alkynes Poster Presentation 2022-12-15
Palladium(II) Catalysed Aminocarbonylation of N,N'-Diaryl-N"-(pyridine-2-ylmethyl)guanidines with Aryl Iodides using CHCl3 and CO Surrogate Poster Presentation 2022-12-15
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