Title Prof. First Name THIRUPATHI Last Name NATESAN
Designation Senior Professor
Department Department of Chemistry
Email tnat@chemistry.du.ac.in
Webpage
Phone.no 9818465378
Employement Info
Employee Type Nature Of Employment
Teaching Permanent
Educational Qualifications
Degree/Certification Name Institution Year of Completion
Ph.D. - Doctor of Philosophy Indian Institute of Science 1998
PG University of Madras 1991
Qualifications
Examination Name Conducting Body Date of Passing
NET Council of Scientific and Industrial Research 15-10-1991
Teaching Experience (Within Institution)
Designation Duration
Research Associate 01-01-1997 To 01-07-1998 (1 years, 6 months)
Postdoctoral Fellow 01-08-1998 To 30-09-1999 (1 years, 1 months, 29 days)
Postdoctoral Fellow 01-10-1999 To 30-09-2002 (2 years, 11 months, 29 days)
Postdoctoral Fellow 01-10-2002 To 31-12-2003 (1 years, 2 months, 30 days)
Reader 09-02-2004 To 09-02-2007 (3 years)
Associate Professor 10-02-2007 To 09-02-2010 (2 years, 11 months, 30 days)
Professor 01-04-2010 To 01-04-2020 (10 years)
Senior Professor 01-04-2020 To 07-01-2023 (2 years, 9 months, 6 days)
Administrative Experience (Within Institution)
Designation Duration
Joint Director 04-10-2021 To 04-10-2023 (2 years)
Research Supervision Overview
PhD Scholars Supervised PhD Degrees Awarded Theses Submitted
0 15 0
M.Phil Scholars Supervised M.Phil Degrees Awarded M.Phil Theses Submitted
0 4 0
Research Publications
Title of Article Type of Publication Name of Journal ISSN Journal Volume Year Link to Article DOI (Digital Object Identifier)
Regioselective Cobalt(II) Catalyzed C−H Functionalization and [3 + 2] Annulation of N‑Arylguanidines with 1,3-Diynes Research Papers in Peer Reviewed Journals The Journal of Organic Chemistry 0022-3263 89 2024 https://pubs.acs.org/journal/joceah 10.1021/acs.joc.3c02252
Syntheses, structural, photophysical and theoretical studies of heteroleptic cycloplatinated guanidinate(1−) complexes bearing acetylacetonate and picolinate ancillary ligands Research Papers in Peer Reviewed Journals RSC Advances 2046-2069 14 2024 https://pubs.rsc.org/en/content/articlelanding/2024/ra/d4ra00828f 10.1039/D4RA00828F
Guanidine-centred reactivity of CNN Pd(II ) pincer complexes including carboxylate-assisted N–H activation and –CH2 – -> –C(O)– oxygenation Research Papers in Peer Reviewed Journals New Journal of Chemistry 1369-9261 48 2024 https://pubs.rsc.org/en/Content/ArticleLanding/2024/NJ/D3NJ05516G 10.1039/d3nj05516g
Efforts to understand the degree of carboxylate substitution in cis-[Pt(S(O)Me2)(guanidine)Cl2]: Synthetic, Structural and DFT Studies Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 247 https://www.sciencedirect.com/journal/polyhedron https://doi.org/10.1016/j.poly.2023.116735
Palladium(II) complexes derived from N,N’− diarylthiourea: Structural aspects and applications toward Suzuki-Miyaura coupling reactions Research Papers in Peer Reviewed Journals Journal of Molecular Structure 0022-2860 1288 https://www.sciencedirect.com/journal/journal-of-molecular-structure doi.org/10.1016/j.molstruc.2023.135797
Influence of the Steric/Electronic Properties of N-Aryl Substituents in Cycloplatinated Guanidinate(1−) Complexes on the Formation of Discrete Pt → Ag Complexes and One-Dimensional Coordination Polymer Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 62 https://pubs.acs.org/journal/inocaj doi.org/10.1021/acs.inorgchem.2c04172
Cobalt(II)-Catalyzed Directed C–H Functionalization/[3+2] Annulation of N-Arylguanidines with Alkynes Research Papers in Peer Reviewed Journals Organic Letters 1523-7052 24 https://pubs.acs.org/journal/orlef7 doi.org/10.1021/acs.orglett.2c02503
Palladium(II) Pincer Complexes Derived From N,N’,N’’-Tris(2-thioanisyl)guanidine. Syntheses, Structural Aspects, Solution Behaviour and Suzuki-Miyaura Coupling Reactions Research Papers in Peer Reviewed Journals ChemistrySelect 2365-6549 7 https://chemistry-europe.onlinelibrary.wiley.com/journal/23656549 doi.org/10.1002/slct.202202778
Reactivity studies of cycloplatinated triarylguanidinato complexes, [Pt(TAG-κC,κN)(X)(S(O)Me2)] (X = Cl and OC(O)CF3) towards Lewis bases, and structural aspects of the products Research Papers in Peer Reviewed Journals Journal of Organometallic Chemistry 0022-328X 959 https://www.sciencedirect.com/journal/journal-of-organometallic-chemistry doi.org/10.1016/j.jorganchem.2021.122200
[6,5] CNN Palladium(II) Pincer Complexes Containing N-Substituted Monoanionic and Dianionic Guanidinate Ligands: Syntheses, Structural Aspects, and Their Utility in Suzuki–Miyaura Coupling Reactions Research Papers in Peer Reviewed Journals Organometallics 0276-7333 40 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/acs.organomet.1c00414
Reactions of Cycloplatinated Guanidine Complexes with Hg(OC(O)CF3)2: Formation of a One-Dimensional Coordination Polymer Containing a Pt2Hg(μ2-S(O)Me2-S,O) Repeating Unit versus a Discrete Pt2Hg2 Complex Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 60 https://pubs.acs.org/journal/inocaj doi.org/10.1021/acs.inorgchem.0c03674
Unusual [Pt{κ2(C,N)}]+ → [Pt{κ2(N,N)}]+ Coordination Mode Flip of the Guanidinate(1−) Ligand in Cationic N,N′,N″-Tris(3,5-xylyl)guanidinatoplatinum(II) Bis(phosphine) Complexes. Syntheses, Structural and Theoretical Studies Research Papers in Peer Reviewed Journals Organometallics 0276-7333 39 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/acs.organomet.0c00408
Syntheses and structural aspects of dinuclear cycloplatinated N,N′,N″-triarylguanidinate(2−) complexes with a novel tridentate μ2-κ2(C,N):κ1N coordination mode Research Papers in Peer Reviewed Journals Journal of Organometallic Chemistry 0022-328X 911 https://www.sciencedirect.com/journal/journal-of-organometallic-chemistry doi.org/10.1016/j.jorganchem.2020.121138
Half Sandwich Electron Deficient N,N′,N′′-Triarylguanidinatoruthenium(II) Complexes: Syntheses, Reactivity Studies, and Structural Aspects Research Papers in Peer Reviewed Journals European Journal of Inorganic Chemistry 1099-0682 2019 https://chemistry-europe.onlinelibrary.wiley.com/journal/10990682c doi.org/10.1002/ejic.201900616
Homoleptic cis- and trans-palladium(II) bis(guanidinato) complexes derived from N-aryl-N′,N″-di(pyridin-2-yl)- and N-aryl-N′,N″-bis(6-methylpyridin-2-yl)guanidines: Catalysts for Heck-Mizoroki coupling reactions Research Papers in Peer Reviewed Journals Journal of Organometallic Chemistry 0022-328X 892 https://www.sciencedirect.com/journal/journal-of-organometallic-chemistry doi.org/10.1016/j.jorganchem.2019.04.009
Influence of cadmium(II) source upon the formation of a discrete monomer [Cd(κ2-OC(O)tBu)2(H2O)2] and a trinuclear heterobimetallic 1D CP, {Na2[Cd(μ5-κ3:κ3-OAc)(μ3-κ2:κ3-OC(O)tBu)(μ3-κ1:κ2-OC(O)tBu)2]·2tBuC(O)OH}∞ Research Papers in Peer Reviewed Journals Inorganica Chimica Acta 1873-3255 489 https://www.sciencedirect.com/journal/inorganica-chimica-acta doi.org/10.1016/j.ica.2019.02.012
Syntheses and structural aspects of six-membered palladacyclic complexes derived from N,N′,N′′-triarylguanidines with N- or S-thiocyanate ligand Research Papers in Peer Reviewed Journals New Journal of Chemistry 1369-9261 43 https://www.rsc.org/journals-books-databases/about-journals/njc doi.org/10.1039/C8NJ04167A
Syntheses, characterization, solution behavior and catalytic activity of trans-[(guanidine)2PdX2] (X = Cl and OC(O)R; R = Me, Ph and tBu) in Heck–Mizoroki coupling reactions involving chloroarenes/methyl acrylate Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 151 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2018.05.022
Critical Role of Anions in Platinum(II) Precursors upon the Structural Motifs of Six-Membered Cycloplatinated N,N′,N″-Triarylguanidines Research Papers in Peer Reviewed Journals ACS Omega 2470-1343 3 https://pubs.acs.org/journal/acsodf doi.org/10.1021/acsomega.8b00782
Probing the factors that influence the conformation of a guanidinato ligand in [(η5-C5Me5)M(NN)X] (NN = chelating N,N′,N′′-tri(o-substituted aryl)guanidinate(1−); X = chloro, azido and triazolato) Research Papers in Peer Reviewed Journals New Journal of Chemistry 1369-9261 42 https://www.rsc.org/journals-books-databases/about-journals/njc doi.org/10.1039/C7NJ03766J
Syntheses, characterisation, and catalytic role of (η5-C5Me5)Rh(iii) guanidinato complexes in transfer hydrogenation (TH) and TH–etherification Research Papers in Peer Reviewed Journals RSC Advances 7 https://www.rsc.org/journals-books-databases/about-journals/rsc-advances/ doi.org/10.1039/C7RA04152G
Six-membered cyclopalladated N,N′,N″-triarylguanidines, [{κ2(C,N)Pd}2(μ-OAc)(μ-Pz)], [κ2(C,N)Pd(μ-Pz)]2 and a novel [AgNO3⊂{{κ2(C,N)Pd}2(μ-NO3)(μ-Pz)}]: Syntheses, reactivity studies, structural aspects, and solution behavior Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 117 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2016.07.008
Syntheses, Structural Aspects, Solution Behavior, and Catalytic Utility of Cyclopalladated N,N′,N″-Triarylguanidines [κ2(C,N))Pd(Pyrazole)2X] (X = Br, OC(O)CF3, and PF6) in Suzuki–Miyaura Coupling Reactions of Aryl Bromides Research Papers in Peer Reviewed Journals Organometallics 1520-6041 35 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/acs.organomet.6b00442
Reactions of Cd(OAc)2·2H2O with variously substituted pyridines. Efforts to unravel the factors that determine structure/nuclearity of the products Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 98 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2015.06.002
Ionic and Neutral Half-Sandwich Guanidinatoruthenium(II) Complexes and Their Solution Behavior Research Papers in Peer Reviewed Journals European Journal of Inorganic Chemistry 1099-0682 2015 https://chemistry-europe.onlinelibrary.wiley.com/journal/10990682c doi.org/10.1002/ejic.201500395
Depalladation of Neutral Monoalkyne- and Dialkyne-Inserted Palladacycles and Alkyne Insertion/Depalladation Reactions of Cationic Palladacycles Derived from N,N′,N″-Triarylguanidines as Facile Routes for Guanidine-Containing Heterocycles/Carbocycles: Synthetic, Structural, and Mechanistic Aspects Research Papers in Peer Reviewed Journals Organometallics 33 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om500837v
Mono- and Dialkyne Insertion Reactions of Cyclopalladated N,N′,N″-Triarylguanidines [κ2(C,N)Pd(μ-Br)]2 and cis-/trans-[κ2(C,N)Pd(Lewis Base)Br]. Scaffolds for Enlarged, Rearranged, and Zwitterionic Palladacycles through Ring Contraction cum Amine–Imine Tautomerization Research Papers in Peer Reviewed Journals Organometallics 1520-6041 33 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om500423q
Insertion Reactions of Six-Membered Cyclopalladated N,N′,N″-Triarylguanidine, [Pd{κ2(C,N)-C6H3Me-3(NHC(NHAr)(═NAr))-2}(μ-Br)]2 (Ar = 2-MeC6H4) with PhC≡C—C(O)OR (R = Me and Et): A Gateway to Second Orthopalladation through Novel Rearrangements Research Papers in Peer Reviewed Journals Organometallics 1520-6041 32 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om4010719
Six-membered [C,N] cyclopalladated sym N,N′,N″-tri(4-tolyl)guanidines: Synthesis, reactivity studies and structural aspects Research Papers in Peer Reviewed Journals Journal of Organometallic Chemistry 0022-328X 741-742 https://www.sciencedirect.com/journal/journal-of-organometallic-chemistry doi.org/10.1016/j.jorganchem.2013.05.030
Mole Ratio Dependent Formation of Mononuclear versus Pentanuclear Zinc(II) Pivalate Complexes and the 'Carboxylate Shift' Process. Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 55 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2013.02.081
Influence of Steric Effect on the Structural Aspects of N,N',N''-Triarylguanidine Derived Six-Membered [C,N] Palladacycles. Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 52 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/j.poly.2012.06.077
Dual Role of Acetate as a Nucleophile and as an Internal Base in Cycloplatination Reaction of sym-N,N′,N″-Triarylguanidines Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic302058u
Synthesis, Reactivity Studies, Structural Aspects, and Solution Behavior of Half Sandwich Ruthenium(II) N,N',N''-Triarylguanidinate Complexes. Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 51 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic201343w
3,5-Lutidine coordinated zinc(II) aryl carboxylate complexes: Precursors for zinc(II) oxide Research Papers in Peer Reviewed Journals Inorganica Chimica Acta 0020-1693 372 https://www.sciencedirect.com/journal/inorganica-chimica-acta doi.org/10.1016/j.ica.2011.01.083
Effects of steric/basic properties of Lewis bases on the degree of aggregation of zinc(II) pivalate complexes Research Papers in Peer Reviewed Journals Inorganica Chimica Acta 0020-1693 370 https://www.sciencedirect.com/journal/inorganica-chimica-acta doi.org/10.1016/j.ica.2011.01.040
Synthesis, Reactivity, Structural Aspects, and Solution Dynamics of Cyclopalladated Compounds of N,N′,N′′-Tris(2-anisyl)guanidine Research Papers in Peer Reviewed Journals Organometallics 1520-6041 30 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om1009445
Synthesis and Conformational Features of Sym N,N',N''-Triarylguanidines. Research Papers in Peer Reviewed Journals Journal of Chemical Sciences 0973-7103 122 https://www.springer.com/journal/12039/ doi.org/10.1007/s12039-010-0017-8
Factors Dictating the Nuclearity/Aggregation and Acetate Coordination Modes of Lutidine-Coordinated Zinc(II) Acetate Complexes. Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 49 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic901100z
Latent cationic palladium(II) phosphine carboxylate complexes for norbornene polymerization Research Papers in Peer Reviewed Journals Journal of Polymer Science Part A: Polymer Chemistry 0887624X, 10990518 47 https://onlinelibrary.wiley.com/journal/26424169 doi.org/10.1002/pola.23125
Comparisons of Phosphorus Ligation Properties in P(CH2NR)3P. Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 46 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic0703070
Reactivity Studies of Cationic Palladium(II) Phosphine Carboxylate Complexes with Lewis Bases: Substitution versus Cyclometalation. Research Papers in Peer Reviewed Journals Organometallics 1520-6041 26 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om070069g
Synthesis and Photoelectron Spectroscopic Studies of N(CH2CH2NMe)3PE (E = O, S, NH, CH2) Research Papers in Peer Reviewed Journals Journal of the American Chemical Society 0002-7863 128 https://pubs.acs.org/journal/jacsat doi.org/10.1021/ja0547533
Synthesis and Reactivity of Cationic Palladium Phosphine Carboxylate Complexes. Research Papers in Peer Reviewed Journals Organometallics 1520-6041 24 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om050356p
An Investigation of Staudinger Reactions Involving Cis-1,3,5-Triazidocyclohexane and Tri(alkylamino)phosphines. Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 43 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic0492845
Reactions of Tris(amino)phosphines with Arylsulfonyl Azides:  Product Dependency on Tris(amino)phosphine Structure Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 42 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic025920s
Mono- and Dianionic Guanidinate Ligands. Reactivity of [iPrN:C(NiPr)2]Ta(NMe2)3 and [(iPrNH)C(NiPr)2]TaCl(NMe2)3 with Me3SiCl and ArNC (Ar = 2,6-Me2C6H4). Research Papers in Peer Reviewed Journals Organometallics 1520-6041 19 https://pubs.acs.org/journal/orgnd7 doi.org/10.1021/om991010f
Group 5 Transition Metal Imido Complexes with Dianionic Guanidinate Ligands Displaying Extended Interactions. Research Papers in Peer Reviewed Journals Chemical Communications 1364-548X 1999 https://www.rsc.org/journals-books-databases/about-journals/chemcomm/ doi.org/10.1039/A906976C
Guanidinate Anions and Dianions. Reactions Involving Alkylguanidines, (RNH)2CNR (R = i-Pr or Cy), Metal Amido Complexes M(NMe2)5 (M = Ta or Nb). Research Papers in Peer Reviewed Journals Journal of Chemical Society, Dalton Transactions 1477-9234 1999 https://pubs.rsc.org/en/journals/journalissues/dt#!recentarticles&adv doi.org/10.1039/A904072B
Cyclotriphosphazanes and Bicyclic Tetraphosphapentazanes Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 1042-6507 144-146 https://www.tandfonline.com/journals/gpss20 doi.org/10.1080/10426509908546232
Oxidative Addition of Tetrachloro-1,2-benzoquinone to λ3-Cyclotriphosphazanes. An Unusual Ring Contraction−Rearrangement Research Papers in Peer Reviewed Journals Inorganic Chemistry 0020-1669 38 https://pubs.acs.org/journal/inocaj doi.org/10.1021/ic980459i
Molybdenum tetracarbonyl complexes of (aryloxy) λ3-cyclotriphosphazanes; X-ray crystal structure of [Mo(CO)4{EtNP(OC6H4Br-4)}3] Research Papers in Peer Reviewed Journals Polyhedron 0277-5387 18 https://www.sciencedirect.com/journal/polyhedron doi.org/10.1016/S0277-5387(98)00315-5
Synthesis, reactivity and structural characterisation of bicyclic tetraphosphapentazanes Research Papers in Peer Reviewed Journals Journal of Chemical Society, Dalton Transactions 1477-9234 1998 https://pubs.rsc.org/en/journals/journalissues/dt#!recentarticles&adv doi.org/10.1039/A801443D
CONFORMATIONS OF (ARYLOXY)-δ3-CY CLOTRIPHOSPHAZANES. SINGLE CRYSTAL X-RAY STRUCTURES OF [EtNP(OR)]3 [R=C6H4Br-2 (CIS), C6H3Me2-2,6 (TRANS)] Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 1563-5325 123 https://www.tandfonline.com/journals/gpss20 doi.org/10.1080/10426509708044215
The Reaction of λ3-Cyclotriphosphazanes with Tetrachloro-o-benzoquinone: an Unusual Ring Contraction-Rearrangement. Research Papers in Peer Reviewed Journals Chemical Communications 1364-548X 1996 https://www.rsc.org/journals-books-databases/about-journals/chemcomm/ doi.org/10.1039/CC9960001703
Preparation, spectral characterization, and single crystal X-ray structures of cis and trans isomers of 2,4,6-trifluoroethoxy-1,3,5-triethyl-1,3,5,2λ5, 4λ5, 6λ5-triazatriphosphorinane-2,4,6-trioxide, [ETNP(O)(OCH2CF3)]3 Research Papers in Peer Reviewed Journals Heteroatom Chemistry 10427163, 10981071 6 https://www.hindawi.com/journals/htrc/ doi.org/10.1002/hc.520060114
New Insights into the Chemistry of Cyclic Phosphorus-Nitrogen Compounds. Research Papers in Peer Reviewed Journals Phosphorus, Sulfur, and Silicon and the Related Elements 10426507, 15635325. 93-94 https://www.tandfonline.com/journals/gpss20 doi.org/10.1080/10426509408021821
Non-Journal Publications
Title of Publication Type of Publication Publisher Role ISBN Year Link to Publication Level
SINGLE COMPONENT CATIONIC PALLADIUM PROINITIATORS FOR THE LATENT POLYMERIZATION OF CYCLOOLEFNS Full Paper in Conference Proceedings/Other United States Patent Application Publication Co-Author 10/976,350 https://patents.justia.com/inventor/natesan-thirupathi International
Research Projects
Project Title Project Type Year Of Sanction Outcome/Output Duration
Cobalt(II) Catalyzed Directed C-H Functionalization of N-Substituted Guanidines with 1,3-Diynes Minor 2022 The outcome was published in the form of poster in the conference and published as a paper. Ongoing since 01-09-2022 (2 years, 2 months, 20 days)
Guanidine containing heterocycles through domino reactions involving N-aryl guanidines and alkynes/1,3-diynes and allenes using cobalt(II) catalysts Minor 2020 The outcome was published in the form of poster in the conference and published as a paper. 01-01-2020 To 15-03-2021 (1 years, 2 months, 14 days)
Cobalt(II) Catalyzed Directed C-H Activation Reactions of N-Substituted Guanidines with 1,3-Diynes and Allenes Minor 2021 The outcome was published in the form of poster in the conference and published as a paper. 29-09-2021 To 15-03-2022 (5 months, 14 days)
sym N,N′,N″-Triarylguanidines as Scaffolds for New Class of Metallacycles and Half Sandwich Complexes of Platinum Group Metals Major 2015 The outcome of the project was published in the form of more than 10 publications and presented in the form of poster and invited talk in several conferences 09-09-2015 To 08-03-2019 (3 years, 5 months, 27 days)
N,N',N"–Triarylguanidine complexes of platinum metal groups Major 2010 The outcome of the project was presented in several conferences and published in peer reviewed journals. 22-04-2010 To 22-10-2013 (3 years, 6 months)
Platinum Group metal complexes on N,N',N"–Triarylguanidines Major 2016 The outcome of the project is presented in several conferences and published in peer reviewed journals. 24-06-2016 To 24-06-2019 (3 years)
Lewis base supported zinc(II) carboxylate complexes and their thermal behaviour Major 2006 The outcome of the project was presented in several conferences and published in peer reviewed journals. 02-11-2006 To 03-06-2010 (3 years, 7 months, 1 days)
Guanidine Scaffold for constructing short and wide bite angle phosphine ligands and their transition metal complexes Major 2005 The outcome of the project was presented in several conference and published in peer reviewed journals. 17-01-2005 To 18-07-2008 (3 years, 6 months, 1 days)
Professional Development Programmes
Programme Title Sponsoring Institution Organizing Institution Role Type of Programme
UGC-Sponsored Refresher Course University Grant Comission University of Delhi Organising Refresher Program
Talk Poster Presented
Name of the Activity Role Date of Activity
Palladium(II) and platinum(II) complexes of N,N',N"-triarylguanidines. Recent findings and ongoing investigations Oral Presentation 28-10-2018
Organo-Platinum and -Plalladium Complexes of N-Arylguanidines Invited Talk 15-12-2022
Synthesis, structural and optical studies of six-membered cycloplatinated guanidines, [Pt{k2(C,N)}{k2(O,O'-acac)}] Poster Presentation 28-10-2018
Reactivity studies of six-membered cycloplatinated guanidines, [Pt{k2(C,N)}(OC(O)CF3)(DMSO)] with Ph2P(CH2)nPPh2 (n = 1-3). Efforts to unravel factors that determine C,N versus N,N coordination modes of N,N',N"-triarylguanidines in the products Poster Presentation 28-10-2018
Formation of mono- and dinuclear palladium pincers derived from picolinamide and picolyl protected unsymmetrical N,N’,N”-trisubstituted guanidines and their role as catalysts in Suzuki-Miyaura coupling reactions. Poster Presentation 11-12-2019
Syntheses of indole N-carboximidamides from unsymmetrical N,N',N"-triarylguanidines through cobalt (II) catalysed directed C-H activation Poster Presentation 11-12-2019
Platinum(II) adducts, cis-[L2PtXX'] (X = X' = Cl (1); X = Cl, X' = OC(O)CH3 (2) and X = X' = OC(O)CF3 (3)) of rigid 2-amino benzimidazole type guanidines, L. Synthetic and structural studies. Poster Presentation 11-12-2019
CNN Palladium(II) Pincer Complexes Derived from Picolyl Based N-Substituted Guanidines. Syntheses, Structures, Reactivity and Catalytic Activity in Cycloisomerisation of 4-pentynoic Acid Poster Presentation 26-09-2021
Cobalt(II) Catalysed Directed C-H Activation/Annulation of N-Arylguanidines with Internal Alkynes Poster Presentation 15-12-2022
Palladium(II) Catalysed Aminocarbonylation of N,N'-Diaryl-N"-(pyridine-2-ylmethyl)guanidines with Aryl Iodides using CHCl3 and CO Surrogate Poster Presentation 15-12-2022
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